472 research outputs found

    Development of Multielement Nanostructured Ceramics Through Solution Route

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    A class of orthogonal polynomials of a new type

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    The purpose of this paper is to study a class of polynomials Fnm(x,λ,ν) associated with a class of m differential equations, where λ is fixed, n is a variable parameter, m is fixed positive integer and ν is a non-negative integer <m. We also obtain all the important properties of this class of polynomials including Rodrigues' formulas, generating function, and recurrence relations. Several special cases of interest are obtained from our analysis

    Effects of virtual acoustics on dynamic auditory distance perception

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    Sound propagation encompasses various acoustic phenomena including reverberation. Current virtual acoustic methods, ranging from parametric filters to physically-accurate solvers, can simulate reverberation with varying degrees of fidelity. We investigate the effects of reverberant sounds generated using different propagation algorithms on acoustic distance perception, i.e., how faraway humans perceive a sound source. In particular, we evaluate two classes of methods for real-time sound propagation in dynamic scenes based on parametric filters and ray tracing. Our study shows that the more accurate method shows less distance compression as compared to the approximate, filter-based method. This suggests that accurate reverberation in VR results in a better reproduction of acoustic distances. We also quantify the levels of distance compression introduced by different propagation methods in a virtual environment.Comment: 8 Pages, 7 figure

    Formation of Silicon Carbide Whiskers from Organic Precursors Via Sol-Gel Method

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    Silicon Carbide (SiC) was synthesized by carbothermal reduction of silica precursor and carbon precursor. The silica precursor was obtained from tetraethoxysilane. Sucrose was used as carbon source. Tetraethoxysilane (TEOS) was hydrolyzed in acidic water (pH = 2). The molar ratio of TEOS-H2O-EtOH was taken as 1:8:2 in the sol-gel processing. Hydrolysed silica sol was polymerized with sucrose to incorporate carbon precursor into the silica network. The gel thus obtained was dried in an oven at 70 oC and at 100 oC. The solid mass obtained on drying was heat treated at 1000 °C in nitrogen atmosphere to obtain the black glass. It was characterized by FTIR, SEM and TGA. The black glass was further heated to 1500 oC in argon to yield silicon carbide. this resulted in formation of β-SiC whiskers

    Studies on synthesis and Reduction of Graphene Oxide from Natural Graphite by using Chemical Method

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    Graphene is a material with rapidly growing interest. It consists of flat monolayer of carbon atoms tightly packed into a two-dimensional (2D) honeycomb lattice and is basic building block for all graphitic materials. Interest in Graphene is because of its excellent mechanical, electrical, thermal, optical properties and its very high specific surface area. Studies have been performed on wet oxidation of natural graphite by using Modified Hummers Method followed by exfoliation and reduction in order toВ  synthesise graphene from Graphite Oxide (GO). Acid route has been followed for oxidation whereas reduction has been carried out in water with hydrazine hydrate and Sodium Borohydrate. It results in to a material with characteristics that are comparable to those of pristine graphite. The reaction at every step has been characterized by using FTIR, TGA, XRD, Raman spectroscopy and surface area measurement

    Separation of Cenospheres from Fly Ashes by Floatation Method

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    Fly-ashes are non-combustible mineral residues which are produced from coal in thermal power plants. Four different types of fly ashes were collected from different power station in Gujarat. Characterization through SEM shows that fly ash contains cenosphere i.e. gas bubble containing ceramic particle independent of their bulk density. Floatation technique was used for the separation of cenosphere from fly ash. Two solvents with extremely different densities were used for the separation of cenospheres. All methods gave approximately yield of less than 1% cenosphere in fly ash. Color of cenospheres varied from gray to almost white and the value of density range from 0.4 – 0.8 g/cc. Further, chemical composition analysis revealed that cenospheres do not contain any high concentration of hazardous elements

    Effect of Additional Particulate Reinforcement on the Properties of Fibrous Ceramic Matrix Composites

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    Composites, generally, consist of two phase i.e. matrix and reinforcement. Here in this work additional phase in terms of micro/nano particles was added in the fiber reinforced ceramic matrix composites and its effect on the final properties of composites was studied. Composites were prepared using sol derived from Tetraethoxysilane (TEOS) and Dimethyldiethoxysilane (DEDMS), and polycarbosilane (PCS) as matrix precursors and SiC fabric as reinforcement. To some composites another phase of solid, micro/nano powder precursor of SiC was added to decrease number of impregnation cycles. Latter composites resulted in higher density. Green composites were post-cured and pyrolyzed. Some of the composites were heated to 1500 °C in argon atmosphere. Composites were characterized for density, microstructure and mechanical properties. It revealed that the resulting matrix was solid glass and addition of SiC powder facilitated the rapid densification. Composites prepared with SiC nanoparticles as well as SiC fabric as reinforcement exhibit higher flexural strength than those made without nanoparticles. The fracture behaviour is also seen to be of mixed mode failure type

    Studies on Fabrication and Characterization of Nanoclay Reinforced Nylon-6 composites: Enhancement of Heat distortion Temperature

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    Organically modified nanoclay (cation exchange capacity of 135 to 145 meq/100 g) was used as nanophase reinforcement for fabrication of nylon-6 nanocomposites. The thickness of clay platelets varied form 1.2 nm to 1.3 nm with 3.485 nm as d-spacing. Nylon 6/nanoclay composites were fabricated with loading of 2.5, 5.0 and 10 wt. % nanoclay via direct melt compounding technique using conventional twinscrew extruder. Processing temperature profile from hopper to header was 230-240-245-260 °C and screw speed was maintained at 180 rpm. The nylon 6/clay nanocomposites were characterized for thermal and mechanical properties. The structural properties were characterized by Differential Scanning Calorimeter (DSC) and X-ray diffraction analysis. The tensile fracture morphology was analyzed by using Scanning Electron Microscope (SEM). DSC nonisothermal curves show an increase in the crystallization temperature with increasing degree of crystallinity. The crystallization rate of the nanoclay reinforced nylon 6 composites was found to be significantly faster than that for the pristine nylon 6 and suggests that the layered silicates act as nucleating centers. XRD result shows that addition of nanoclay by this technique favors the formation of γ-crystalline phase in nylon 6/nanoclay composites. Due to this, there is substantial enhancement in the tensile strength and Izod impact strength. A variation from 700 to 971 Kg/cm2 for tensile strength and from 3.0 to 3.4 Kg.cm/cm of notch for Izod impact strength. The detailed results are presented

    Synthesis and Characterization of Hydroxyapatite Nanoparticles using Sol-Gel Method

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    Hydroxyapatite (HAp) is a unique material having high adsorption capacity of heavy metals, high ion exchange capacity, high biological compatibility, low water solubility, high stability under reducing and oxidizing conditions, availability and low cost. Hydroxyapatite nanoparticles have been synthesized by Sol-gel method using Calcium nitrate tetrahydrate [Ca(NO3)2•4H2O] and Phosphorus pentaoxide (P2O5) as starting reactants. The addition of Phosphorus pentaoxide to Calcium nitrate tetrahydrate was carried out slowly with simultaneous stirring. After addition, solution was aged for 10 minutes for maturation. The precipitate was dried at 80 °C overnight and further heat treated at 550 °C for 2 hours. The dried and calcined particles were characterized by X-ray diffractometry, Fourier transform infra-red spectroscopy and Thermo gravimetric analysis. The particle size and morphology were studied using transmission electron microscopy. TEM examination of the treated powders displayed particles of polygon morphology with dimensions 20-50 nm in length. The FT-IR spectra for sample confirmed the formation of hydroxyapatite

    MSVIPER: Improved Policy Distillation for Reinforcement-Learning-Based Robot Navigation

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    We present Multiple Scenario Verifiable Reinforcement Learning via Policy Extraction (MSVIPER), a new method for policy distillation to decision trees for improved robot navigation. MSVIPER learns an "expert" policy using any Reinforcement Learning (RL) technique involving learning a state-action mapping and then uses imitation learning to learn a decision-tree policy from it. We demonstrate that MSVIPER results in efficient decision trees and can accurately mimic the behavior of the expert policy. Moreover, we present efficient policy distillation and tree-modification techniques that take advantage of the decision tree structure to allow improvements to a policy without retraining. We use our approach to improve the performance of RL-based robot navigation algorithms for indoor and outdoor scenes. We demonstrate the benefits in terms of reduced freezing and oscillation behaviors (by up to 95\% reduction) for mobile robots navigating among dynamic obstacles and reduced vibrations and oscillation (by up to 17\%) for outdoor robot navigation on complex, uneven terrains.Comment: 6 pages main paper, 2 pages of references, 5 page appendix (13 pages total) 5 tables, 9 algorithms, 4 figure
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